Abstract
“By 2016, flexible barrier manufacturing will be a market of more than US$1 Billion.”
Description
Although it is possible to print many different kinds of electronic displays,
in order for them to be commercially successful, they must be robust enough to
survive for the necessary time and conditions required of the display. This
condition has been a limitation of many printable electronic displays. Beyond
printability and functionality, one of the most important requirements is
encapsulation. Many of the materials used in printed electronic displays are
chemically sensitive, and will react with many environmental components.
This concise and highly targeted report from IDTechEx technology analyst Dr
Harry Zervos gives an in-depth review of the issues, as well as forecasts for
OLEDs and OPV, in order to understand the influence that the development of
flexible barriers will have on the mass deployment and adoption of flexible
electronics and photovoltaics.
A large opportunity lies in the development of devices in a flexible form
factor, allowing them to be more robust, lightweight and versatile in their
use.
However, many of the materials used in OLED displays and organic photovoltaics
are sensitive to the environment, limiting their lifetime. These materials can
be protected using substrates and barriers such as glass and metal, but this
results in a rigid device and does not satisfy the applications demanding
flexible devices. Plastic substrates and transparent flexible encapsulation
barriers can be used, but these offer little protection to oxygen and water,
resulting in the devices rapidly degrading.
In order to achieve device lifetimes of tens of thousands of hours, water
vapor transmission rates (WVTR) must be 10-6 g/m2/day, and oxygen transmission
rates (OTR) must be < 10-3 cm3/m2/day. For Organic Photovoltaics, the
required WVTR is not as stringent as OLEDs require but is still very high at a
level of 10-5 g/m2/day. These transmission rates are several orders of
magnitude smaller than what is possible using any plastic substrate, and they
can also be several orders of magnitude smaller than what can be measured
using common equipment designed for this purpose. For these (and other)
reasons, there has been intense interest in developing transparent barrier
materials with much lower permeabilities.
This concise and unique report from IDTechEx gives an in-depth review of the
needs, emerging solutions and players.
It addresses specific topics such as:
- Companies which are active in the development of high barrier films and
their achievements on the field to date.
- Surface smoothness and defects (such as cracks and pinholes) and the
effect that these characteristics would have on the barrier behavior of the
materials studied.
- Traditional methods of measurement of permeability are reaching the end of
their abilities. The MOCON WVTR measurement device, which has been an industry
standard, cannot give adequate measurements at the low levels of permeability
required for Organic Photovoltaics and OLEDs. Other methods of measurement and
equipment developed are being discussed.
- Forecasts for OLEDs and OPV, in order to understand the influence that the
development of flexible barriers would have at the mass deployment and
adoption of these technologies.
Report Statistics
- Last update : Jan 2012
- Forecasts to: 2021
- Total Number of Pages: 91
- Total Number of Tables: 8
- Total Number of Figures: 48
Table of Contents
1. SCOPE
2. INTRODUCTION TO ENCAPSULATION
3. SURFACE SMOOTHNESS - DEFECTS
- 3.1. Important considerations of surface smoothness
- 3.2. Micro Defects
- 3.2.1. Crystalline regions
- 3.2.2. Pinholes
- 3.2.3. Smoothness / Cracks-Scratches
- 3.2.4. Nanodefects
4. COMPANIES
- 4.1. 3M
- 4.2. Amcor Flexibles Singen GmbH
- 4.3. CPI
- 4.4. Fraunhofer - POLO Alliance
- 4.5. GE
- 4.6. Tera Barrier
- 4.7. Vitex
- 4.8. Other technologies - High barrier adhesives
- 4.9. Best performing barriers developed to date
5. BARRIER MEASUREMENTS
- 5.1. The Calcium test
- 5.2. MOCON
- 5.3. Illinois Instruments
- 5.4. Fluorescent Tracers
- 5.5. Black Spot Analysis
- 5.6. Tritium Test
- 5.7. CEA
- 5.8. 3M
- 5.9. IMRE
- 5.10. Mass Spectrocopy - gas permeation (WVTR & OTR potential applications)
6. FORECASTS FOR BARRIER FILMS FOR FLEXIBLE ELECTRONICS 2011-2021
- 6.1. The potential significance of organic and printed inorganic
electronics
- 6.2. Forecasts for flexible electronics 2011-2021
- 6.3. Barrier films market size
7. CONCLUSIONS
8. REFERENCES
APPENDIX 1: ATOMIC LAYER DEPOSITION
APPENDIX 2: IDTECHEX PUBLICATIONS AND CONSULTANCY
TABLES
- 2.1. Water vapor and oxygen transmission rates of various materials
- 2.2. Requirements of barrier materials
- 3.1. Oxygen transmission rates of polypropylene with various coatings.4, 7
- 4.1. Overview of promising high barrier technologies
- 5.1. Lower detection limits of several barrier performance measurement
techniques
- 6.1. Leading market drivers 2021
- 6.2. Total market value of flexible vs. rigid electronics 2011-2021
- 6.3. Barrier Layer Market Forecasts 2011-2021
FIGURES
- 1.1. Examples of flexible OLED displays by SONY and AddVision
- 1.2. Flexible OLED fabricated using IMRE's high barrier substrate and
encapsulation technique4
- 1.3. Flexible Solar Cell developed by Fraunhofer ISE
- 2.1. Schematic diagrams for encapsulated structures a) conventional b)
laminated c) deposited in situ4
- 2.2. Scanning electron micrograph image of a barrier film cross section6
- 3.1. Visual defects of a selection of materials with barrier films
highlighted through calcium corrosion test. Optical microscope magnification
10x.44
- 3.2. SEM pictures of the Atmospheric Plasma Glow Discharge deposited
silica-like films on polymer substrates. Left: Film with embedded dust
particles . Right: uniform film27
- 3.3. OTR as a function of defect density, the correlation between defect
density and the oxygen transmission rate
- 3.4. SEM image of a pinhole defect formed from a dust particle32
- 3.5. Scanning electron microscope image of ITO coated on parylene/polymer
film34
- 3.6. The measurement of OLED's lifetime of SiON/PC/ITO and
SiON/parylene/PC/parylene/ITO substrate34
- 4.1. Calcium test results demonstrating superior WVTR performance
- 4.2. 3M barrier film development roadmap
- 4.3. Amcor (formerly Alcan) Packaging flexible barrier based on PET and
SiOx47
- 4.4. DuPont Displays technology pipeline
- 4.5. Scanning electron micrograph of a thin hybrid polymer coating on SiOx
deposited on a flexible PET film 46
- 4.6. OTR values achieved with different POLO multilayers46
- 4.7. Schematic of cross section of graded barrier coating and complete
barrier film structure1.
- 4.8. Transparency of GE's UHB film versus wavelength
- 4.9. Examples of polymer multi-layer (PML) surface planarization a) OLED
cathode separator structure b) high aspect ratio test structure.3, 8
- 4.10. Vitex multilayer deposition process8.
- 4.11. SEM cross section of Vitex Barix material with four dyads.
- 4.12. Optical transmission of Vitex Barix coating8.
- 4.13. Edge seal barrier formation by deposition through shadow masks10
- 4.14. Three dimensional barrier structure. Polymer is shown in red, and
oxide (barrier) shown in blue10
- 4.15. Schematic of flexible OLED with hybrid encapsulation31
- 4.16. Corning flexible glass showcased at SID 2011
- 4.17. Matchless: AGC's ultra-thin sheet glass may be thin, but it can take
the heat
- 4.18. AGC's ultra-thin sheet glass rolled into a coil
- 4.19. Area sealing55
- 4.20. DELO's light curing adhesive solution for electrophoretic displays55
- 4.21. Performance characteristics of DELO's light-curing materials55
- 4.22. Specifications on WVTR for different applications, as seen by Vitex
Systems36
- 4.23. 3M specifications on WVTR and OTR for high barrier applications with
stringent requirements 14
- 5.1. 2.25 mm2 area of a 50 nm layer of Ca deposited onto barrier coated
PET viewed through the substrate. i. Image after 1632 h of exposure to
atmosphere; ii. Image analysis whereby the grey scale of Ca degradation is
processed to yiel
- 5.2. A simple set-up for measuring optical transmission of calcium test
cells48
- 5.3. MOCON's Aquatran™ Model 138
- 5.4. MOCON's Aquatran™ schematic38
- 5.5. MOCON's OX-TRANR Model 2/1039
- 5.6. Silica induced black spots, letters A & B mark black spots with a
centralized black dot (silica particle)32
- 5.7. Black spot formation and growth mechanisms 32
- 5.8. General Atomics HTO WVTR testing apparatus40
- 6.1. Total market value of flexible vs. rigid electronics 2011-2021
- 6.2. Barrier Layer Market Forecasts 2011-2021
- 6.3. Size of opportunity
- 7.1. The iRex iLiad and the Amazon Kindle rigid e-book readers
- 7.2. PVI's flexible electrophoretic display and color electrophoretic
display by SAMSUNG LCD, demonstrated at SID 2008
- 7.3. Lithium test sample with thin film encapsulation after 24 hrs in the
damp heat test at 85°C/85% relative humidity. B. Similar lithium test
sample after 200 hrs in the same damp heat test with optimized barrier
structure. [42]
